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Today,
coatings manufacturers have to face customer expectations, which are not
in every case realizable with conventional polymer chemistry. Approaches
to improve mechanical and other properties with inorganic nanoparticles
were found and started a hype beginning in the 1990’s which was followed
by disillusionment and unmet expectations due to incompatibility,
expensive dispersion techniques or simply a visible haze of the still
agglomerated “nanoparticles”.
In only
a few coating systems today nanoparticles are used. The reason for this
is mainly the “inorganic” behaviour which causes the still omnipresent
compatibility and/or haze problems.
A new
approach which overcomes these drawbacks are core/shell particles,
consisting of an inorganic core and a shell of grafted organic polymers.
These
particles can be synthesized as bulk or almost transparent dispersions
in common solvents and can be easily formulated with a variety of resins
to yield haze-free glossy coatings, even on deep black surfaces.
Variation of polymer chemistry provides every means to adapt the
nanoparticles to the needs of the customer.
Scratch and abrasion tests show that the scratch resistance of OEM
series clearcoats can be significantly increased and that repair
coatings can achieve the scratch resistance of OEM coatings. |